Yes, I'm aware of engine 'efficiency'. I know thermodynamics well as in a previous career I worked for GE at the aircraft engine plant in Evandale OH as an engineer for compressors, combustors, and turbines.
Modern engines are pretty efficient. Of course 100% of the BTUs in a gallon of fuel do not go into moving the car forward. However, all things being equal, you can draw a very good general conclusion of what happens when fuels are blended. Closer tolerances, better lubricants, etc all contribute to better efficiency. Tires that have less rolling resistance, better
wheel bearings, all contribute to overall efficiency (as does the transmission) of the system (car).
Again, as an example, I said if you have 10 gallons of pure gasoline, and that takes you 500 miles, your fuel efficiency is 50 miles per gallon. I don't really care about the 'losses' to heat, overcoming friction, etc. The fact is if I have 10 gallons of fuel that takes me 500 miles, then I've distilled the problem past the heat and friction factors. So yes, I and say that the BTUS in that gallon of fuel have taken me down the road as the "overhead" of producing heat and overcoming friction have already been met.
If I have 10 gallons of fuel and have expended it to move my car 500 miles, then I have expended 1.14 million BTUS of energy to go that distance. So what if some of it was spent overcoming friction or producing excess heat, or overcoming the rolling resistance of the tires. If I reduce the amount of pure gasoline in that 10 gallons by 10 percent, I still have to produce heat, I still have to pump oil and overcome the rolling resistance of the same 4 tires. SO that then has LESS BTUs and I travel shorter distance.
I ride a Suzuki motorcycle. If I burn E10 in it, my mileage does not drop 10%. The mileage decrease (not accounting for COLD/freezing weather) amounts to about 4.5% or so. Which works out, since I have a 4 gallon tank, when I replace it with E10, I have 3.6 gallons of pure gas mixed with .4 gallon of ethanol. The available BTUS are less, so I drive a bit less on a full thank. Changes in my riding habits and fuel are very readily apparent and recordable over a short period of time.
And if you look at 10 gallons of pure gasoline compared to 10 gallons of E85, it holds up well:
1 gal pure gas has approximately 1,140,000 BTU by volume.
1 gal of ethanol has approximately 76,000 BTU by volume.
Blend it to E85, and for example, you have 10 gallons of E85.
In that, you have 1.5 gal of pure gasoline = 171,000 BTU.
8.5 gal of ethanol equals approximately 646,000 BTU.
Add them and you have 817,000 BTU. By comparison, 10 gallons of pure gasoline has approximately 1,140,000 BTU.
Simple math shows us that, in this example, E85 has about 72% the available BTUS by VOLUME of pure gasoline. SO that 10 gallons of fuel, instead of taking you 500 miles down the road, can only propel you 360 miles down the road. That's REALLY close to the E85 is about 25% less efficient than gasoline argument. In an E85 capable engine, because it does not change the compression ratio to compensate for the fuel. If you toss out the losses and just compare the end result, it holds. It really doesn't matter that you have loses in overcoming friction or heat - that's built into the 'cost' of doing business. If I burn 10 gallons of fuel to get me 500 miles, it doesn't matter that my engine is 35% efficient - the END result is that I STILL combust 10 gallons of fuel to go 500 miles, all else being equal. If I install a set new tires that have low-rolling resistance tire, my engine efficiency does not change, does it? But I can go 510 miles, so I have burned less fuel, or expended less BTUs in the fuel in my tank, to go that distance.
Now if we actually are able to use butanol instead of ethanol, we're back at relatively decent comparisons to gasoline - butanol is almost on par with gasoline in terms of BTUs by volume, and can be run in an unmodified engine. We should argue engine efficiency in the Physics.org forums..